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You can power up a computer by USB I think. You can enable that in the setup. The problem is that the usb device needs to get power all the time so a remote with an external powered IR-receiver should do the job. I too thought about that but I already have the MCE 2005 remote which is only USB powered and it's dead as long as the computer is turned off

For sure some guys here have that function already! The have a lot of energy to develop handy things!