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The power button and volume buttons are programmable. See here for the Microsoft PDF manual, you'll need to join the forum before you can download it.

http://www.xpmediacentre.com.au/community/downloads.php?do=file&id=49

Or you can read the first post in this thread, it's the same information.

http://www.xpmediacentre.com.au/community/showthread.php?t=1677