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In my setup, the TV card will show video using the defult codecs provided with MP, as well as a few others.

Have you tried installing the intervideo codecs?

Also  I have rechecked my CPU percentage and it seems to be at 100%.

I'm not having too much success getting it to work satisfactorly and from reading lots of other threads, software decoding/encoding cards such as this one don't seem to perform that well with this software.