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Oookay, got it. It's very simple - and very annoying, if you come from the old variants...

The ASP.net application pool will NOT show up in IIS 10.x, even after you installed .NET, MVC3 and ASP.Net. It is integrated into the standard app pools.

So, all you have to do: Use the standard app pool (Net 4.0, integrated pipeline) and enable 32 bit applications. Everything works fine, then. *sigh*

I spent hours and hours on that...