then it means that the problem lays not on your TV delaying the picture comparing to audio (assumnig your amp has a lag near to 0) - or what crappy firmware TV has that produces different picture delays depending on input signal?I cannot adjust it in LAV Audio Decoder because depending on source (Video, TV - even which channel/program) is different.
You should first find out where this lipsync problem comes from, and then fight the root source